The Search for the Next Super Material

Graphene was considered important enough that its inventors received a Nobel Prize. Now the search is on for other 2D wonder materials.

If you turn over a rock and find a gold nugget, you’re going to start turning over more rocks. Back in 2004, a gold nugget known as graphene was discovered in a lab where a sheet of carbon, one atom thick was produced. Graphene, hailed as a super material, was considered important enough that its inventors, Andre Geim and Konstantin Novoselov, received the Nobel Prize in Physics in 2010.
 
Materials this thin have since come to be known as 2D materials. While it has taken awhile, as scientists learn to make and use this material, for commercial applications to hit the market, there can be little doubt that graphene is going to become big business. Consider the range of basic properties that include extreme light weight, exceptional strength and electrical conductivity at potentially low cost. Add to this, biocompatibility, optical transparency, and selective permeability and you have a material juggernaut.

No wonder the search is on for other 2D wonder materials. These two-dimensional workhorses could become so important in the future, that the primary question one might ask of any new material is, “2D or not 2D?”

Mitch Jacoby is a PhD chemist who has studied 2D materials, written about them , and come up with a classification that divides them into five different groups. None of them are as far along in their development as graphene, so it’s difficult to say which one might be the next wonder material. In fact, some of these are so early-stage that they can’t yet be separated from the substrate upon which they are produced. Many though, have achieved freestanding status and considerably more. Let’s take a look at the groups.

 

Graphene

The structure of graphene is a flat hexagonal grid of carbon atoms. Image source: UCL Mathematical and Physical Sciences, Flickr

 

The first are MXenes. These were discovered by Drexel scientists while developing improved anodes for Li-ion batteries. In simplified terms, they are electrically conducting carbides and nitrides. Jacoby describes them as, “electrically conductive, strong, flexible, and durable—ideal properties for electrodes in energy storage and wearable technology.” The Drexel team has demonstrated that MXenes can also serve as lightweight, inexpensive shielding materials to protect cell phones and other devices from electromagnetic interference. Until recently, MXenes could only be produced as powders. Now they can be made into thin, flexible films.

Next are the Xenes.  These are elements other than carbon, that can potentially be made into a single layer.  These include Boron, Silicon, Phosphorus, Germanium, and Tin (B, Si, P, Ge, and Sn). In 2D form they get “-ene” appended as a suffix.  According to Jacoby, “These materials, which include borophene, silicene, phosphorene, germanene, and stanene, all share a buckled or corrugated shape—unlike graphene’s flat sheets—and sport atoms arranged in a honeycomb lattice. Silicene, phosphorene, and borophene are the most studied of the family.” Silicene, unlike graphene, has a band gap and is most studied for fast electronics. Phosphorene has excellent electrical characteristics too, but it degrades in air unless protected. Several of these, including borophene have potential for energy storage.

Organic

Comments

It seems that the majority of these materials include the carbon atom, which is not at all surprising, given that carbon is a very special case. Consider that there is a whole separate area of chemistry called "Organic Chemistry", based on carbon. So while Graphene could be expected, the other materials are less obvious. So it will be quite interesting to see what is actually produced through the additional research.

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